Задайте ограничение на array_agg()

select id[1], id[2]
from (
    SELECT array_agg("Esns".id ) as id
    FROM public."Esns", 
         public."PurchaseOrderItems" 
    WHERE 
        "Esns"."PurchaseOrderItemId" = "PurchaseOrderItems".id 
        AND "PurchaseOrderItems"."GradeId"=2 
) s

или ако искате изхода като масив, можете да отрез то:

SELECT (array_agg("Esns".id ))[1:2] as id_array
FROM public."Esns", 
     public."PurchaseOrderItems" 
WHERE 
    "Esns"."PurchaseOrderItemId" = "PurchaseOrderItems".id 
    AND "PurchaseOrderItems"."GradeId"=2